代码

from urllib import request, parse

url = 'http://httpbin.org/post'

headers = {
    "Accept": "text/html,application/xhtml+xml,application/xml;q=0.9,image/webp,image/apng,*/*;q=0.8,application/signed-exchange;v=b3",
    "Accept-Language": "zh-CN,zh;q=0.9,en;q=0.8,en-US;q=0.7",
    "Host": "httpbin.org",
    "Upgrade-Insecure-Requests": "1",
    "User-Agent": "Mozilla/5.0 (Windows NT 10.0; Win64; x64) AppleWebKit/537.36 (KHTML, like Gecko) Chrome/77.0.3865.90 Safari/537.36"
}

dict = {
    'Lula': 'Study'
}

data = bytes(parse.urlencode(dict), encoding='utf-8')
req = request.Request(url=url, data=data, headers=headers, method='POST')
response = request.urlopen(req)
print(response.read().decode('utf-8'))

运行